The way the sender information is stored is different on different account types. The supported way to query actual email account settings is via the configuration API - InTheHand.WindowsMobile.Configuration.ConfigurationManager. The provider to use is the EMAIL2 provider. We don't currently have a managed wrapper around that provider so you'll have to build the XML document yourself. The provider is documented here:-
http://msdn.microsoft.com/en-us/library/aa457968.aspx
Peter